For some reason, PlatformIO hasn’t merged support for other RP2040 boards to its platform. So we have to do it manually.
PIO Home > Platforms > Advanced Installation and add:
https://github.com/maxgerhardt/platform-raspberrypi.git

It has support for lots of RP2040-based boards. The full list is here.
Pins

My test code:
#include <Arduino.h>
#include <Adafruit_NeoPixel.h>
const int pin_0 = 0;
const int pin_1 = 1;
const int pin_2 = 2;
const int pin_3 = 3;
const int pin_4 = 4;
const int pin_6 = 6;
const int pin_7 = 7;
const int pin_26 = 26;
const int pin_27 = 27;
const int pin_28 = 28;
const int pin_29 = 29;
const int user_led_green = 16;
const int user_led_red = 17;
const int user_led_blue = 25;
const int rgb_power_pin = 11;
const int rgb_data_pin = 12;
constexpr int num_of_pins = 16;
int all_pins[num_of_pins] = {
pin_0,
pin_1,
pin_2,
pin_3,
pin_4,
pin_6,
pin_7,
pin_26,
pin_27,
pin_28,
pin_29,
user_led_green,
user_led_red,
user_led_blue,
rgb_power_pin,
rgb_data_pin
};
constexpr int NUM_RGB_COLORS = 5;
int rgb_colors[NUM_RGB_COLORS][3] = {
{254,10,10},
{10,254,10},
{10,10,254},
{254,254,10},
{10,254,254}
};
// https://learn.microsoft.com/en-us/cpp/cpp/constexpr-cpp?view=msvc-170&viewFallbackFrom=vs-2019
constexpr int RGB_PIXELS = 1;
constexpr int DELAY_TIME = 500;
Adafruit_NeoPixel pixels(RGB_PIXELS, rgb_data_pin, NEO_GRB + NEO_KHZ800);
void setup() {
Serial.begin(115200);
for (int i = 0; i < num_of_pins; i++){
pinMode(all_pins[i], OUTPUT);
}
digitalWrite(rgb_power_pin, HIGH); // RGB Power ON
pixels.begin();
}
void loop() {
// Pins test
for (size_t i = 0; i < (num_of_pins-2); i++){
digitalWrite(all_pins[i], HIGH);
delay(DELAY_TIME);
digitalWrite(all_pins[i], LOW);
delay(DELAY_TIME);
}
// RGB LED test
for (size_t i = 0; i < NUM_RGB_COLORS; i++){
pixels.clear();
pixels.setPixelColor(0, pixels.Color(rgb_colors[i][0], rgb_colors[i][1], rgb_colors[i][2]));
pixels.show();
delay(DELAY_TIME);
}
pixels.clear();
pixels.setPixelColor(0, pixels.Color(0,0,0));
pixels.show();
}